Green synthesis of cobalt and iron incorporated citric acid/ β ‐cyclodextrin composites: Efficient H 2 O 2 scavengers
نویسندگان
چکیده
Sonochemical procedure was used to synthesize Co/β-cyclodextrin complex. For the first time, Fe/β-cyclodextrin complex also synthesized in alkaline media. Moreover, β-cyclodextrin modified by citric acid (CA) and reacted with metal salts under ultrasonic irradiation. The prepared catalysts were characterized using EDX, UV–vis FTIR analytical techniques. highest incorporation of into observed cross linked β-CD. catalase like activity (peroxide scavenging) Co/β-CD Fe/β-CD complexes composites evaluated UV–visible spectrophotometer their superoxide scavenging capacity measured pyrogallol method. Co3/CA-β-CD showed best mimetic (93.2%) even comparison enzyme extracted from potato. Therefore, cobalt acid/β-CD are promising candidates for H2O2 scavenging. By contrast Fe3/CA-βCD had stronger capability eliminate anion radicals.
منابع مشابه
Citric acid as an efficient and green catalyst for the synthesis of hexabenzylhexaazaisowurtzitane (HBIW)
The condensation of benzylamine with glyoxal leads to Hexabenzylhexaazaisowurtzitane (HBIW) in acetonitrile solvent with citric acid as a green catalyst under both conventional stirring and ultrasonic irradiation conditions. The influence of four variables, including the amount of catalyst, solvent, reaction time and ultrasonic power, on the reaction yield was investigated. The results showed t...
متن کاملCitric acid as an efficient and green catalyst for the synthesis of hexabenzylhexaazaisowurtzitane (HBIW)
The condensation of benzylamine with glyoxal leads to Hexabenzylhexaazaisowurtzitane (HBIW) in acetonitrile solvent with citric acid as a green catalyst under both conventional stirring and ultrasonic irradiation conditions. The influence of four variables, including the amount of catalyst, solvent, reaction time and ultrasonic power, on the reaction yield was investigated. The results showed t...
متن کاملcitric acid as an efficient and green catalyst for the synthesis of hexabenzylhexaazaisowurtzitane (hbiw)
the condensation of benzylamine with glyoxal leads to hexabenzylhexaazaisowurtzitane (hbiw) in acetonitrile solvent with citric acid as a green catalyst under both conventional stirring and ultrasonic irradiation conditions. the influence of four variables, including the amount of catalyst, solvent, reaction time and ultrasonic power, on the reaction yield was investigated. the results showed t...
متن کاملOne-pot three component synthesis of 2-amino-4H-chromenes under green and high efficient conditions
A simple, mild and high efficient procedure for one pot three component synthesis of 2-amino 4-H chromene derivatives was studied. The reaction was performed in water using aryl aldehydes, malononitrile and resorcinol, phloroglucinol or naphthole in the presence of N-methyl D-glucamine (Meglumine) as a green high efficient catalyst. The reaction was studied in thermal, microwave (MW) and ultras...
متن کاملOne-pot three component synthesis of 2-amino-4H-chromenes under green and high efficient conditions
A simple, mild and high efficient procedure for one pot three component synthesis of 2-amino 4-H chromene derivatives was studied. The reaction was performed in water using aryl aldehydes, malononitrile and resorcinol, phloroglucinol or naphthole in the presence of N-methyl D-glucamine (Meglumine) as a green high efficient catalyst. The reaction was studied in thermal, microwave (MW) and ultras...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Applied Organometallic Chemistry
سال: 2021
ISSN: ['0268-2605', '1099-0739']
DOI: https://doi.org/10.1002/aoc.6505